Opeth (Progressive Rock/Progressive Metal)
A Swedish metal band that explores whos playing contains elements of 70's progressive rock and jazz, and fronted by Mikael Akerfeldt, a great vocalist whether hes singing, screaming, growling, or bree-breeing, and has impressive classically-influenced guitar skills. Their songs juxtapose brutal and intense death metal sections with soft, minimalistic folky and jazzy sections, and they don't have one single bad song across their 15+ year career. They are also becoming kind of popular right now.
http://www.youtube.com/watch?v=HFFWDUhuMDg
Ulver (Experimental/Electronica/Black Metal/Ambient)
A trio of musical geniuses from Norway that has covered virtually every genre known to man, from black metal to trip hop. Their music is some of the most creative and original out there.
Ayreon (Metal/Electronica/Folk)
A metal opera written and produced by Dutch musician Arjen Anthony Lucassen, an amazing producer. The music is impressive, it combines many genres, mainly metal and electronica, but also some folk and ethnic music. Guest vocalists range from Bruce Dickinson to Devin Townsend. Ayreon is known for their awesome layered female vocals and sci-fi/fantasy based lyrics.
http://www.youtube.com/watch?v=qsJ_YqIJ0YA