Snowbound from Earthbound (by bLind) gets me pretty pumped, as does Chekan Winter. Try virt's "Crystal Flash", it's pretty damned good (twenty minutes long), as well as his "Get on the Bus" (my favorite remix EVER). Triforce Majeure by Disco Dan - in fact, pretty much anything by Disco Dan, virt, or bLind is awesome. chthonic has some good stuff, but I'm not sure if it's what you're looking for. "Simon's Town" is pretty badass too. "Time's Scar" from Chrono Cross (the original one) is awesome, if a little short. Kingdom Hearts' "Another Side, Another Story (Deep Dive)" song, if you can get ahold of it (hint: AIM me) is pretty awesome, as is Advent Children's "For the Reunion".
As far as anime songs go, the Read or Die main theme (preferably the Long Version from the OVA OST and the Hong Kong and Public Pressure versions from the TV OST's) is an absolute must - very Bond-esque, definitely one of the best in terms of pure energy. No vocals either. Actually, most of the songs on those OST's are pretty good.